Efficient Preparations of Fluorine Compounds

The definitive guide to creating fluorine-based
compounds--and the materials of tomorrow

Discovered as an element by the French chemist Henri Moissan in
1886, through electrolysis of potassium fluoride in anhydrous
hydrogen fluoride--"le fluor," or fluorine, began its chemical
history as a substance both elusive and dangerous. With a slight
pale yellow hue, fluorine is at room temperature a poisonous
diatomic gas. Resembling a spirit from a chemical netherworld,
fluorine is highly reactive, difficult to handle, yet very
versatile as a reagent--with the power to form compounds with
almost any other element.

Comprising 20% of pharmaceutical products and 30% of
agrochemical compounds, as well as playing a key role in electric
cars, electronic devices, and space technology, compounds
containing fluorine have grown in importance across the globe.
Learning how to safely handle fluorine in the preparation of
innovative new materials--with valuable new
properties--is of critical importance to chemists today.
Bringing together the research and methods of leading scientists in
the fluorine field, Efficient Preparations of Fluorine
Compounds is the definitive manual to creating, and
understanding the reaction mechanisms integral to a wide variety of
fluorine compounds. With sixty-eight contributed chapters, the
book's extensive coverage includes:

* Preparation of Elemental Fluorine

* Synthesis Methods for Exotic Inorganic Fluorides with Varied
Applications

* Introduction of Fluorine into Compounds via Electrophilic and
Nucleophilic Reactions

* Direct Fluorination of Organic Compounds with Elemental
Fluorine

* Efficient Preparations of Bioorganic Fluorine Compounds

* Asymmetric Fluorocyclization Reactions

* Preparations of Rare Earth Fluorosulfides and
Oxyfluorosulfides

The book offers methods and results that can be reproduced by
students involved in advanced studies, as well as practicing
chemists, pharmaceutical scientists, biologists, and environmental
researchers. The only chemical resource of its kind, Efficient
Preparations of Fluorine Compounds--from its first
experiment to its last--is a unique window into the centuries
old science of fluorine and the limitless universe of
fluorine-based compounds.

Autorentext
HERBERT W. ROESKY, PhD, is Professor Emeritus of
Chemistry at the University of Göttingen and past president of
the Academy of Sciences of Göttingen. He is a recipient of the
ACS Award for Creative Work in Fluorine Chemistry and the H.
Moissan Award in Fluorine Chemistry.

Zusammenfassung
The definitive guide to creating fluorine-based compoundsand the materials of tomorrow Discovered as an element by the French chemist Henri Moissan in 1886, through electrolysis of potassium fluoride in anhydrous hydrogen fluoride"le fluor," or fluorine, began its chemical history as a substance both elusive and dangerous. With a slight pale yellow hue, fluorine is at room temperature a poisonous diatomic gas. Resembling a spirit from a chemical netherworld, fluorine is highly reactive, difficult to handle, yet very versatile as a reagentwith the power to form compounds with almost any other element. Comprising 20% of pharmaceutical products and 30% of agrochemical compounds, as well as playing a key role in electric cars, electronic devices, and space technology, compounds containing fluorine have grown in importance across the globe. Learning how to safely handle fluorine in the preparation of innovative new materialswith valuable new propertiesis of critical importance to chemists today. Bringing together the research and methods of leading scientists in the fluorine field, Efficient Preparations of Fluorine Compounds is the definitive manual to creating, and understanding the reaction mechanisms integral to a wide variety of fluorine compounds. With sixty-eight contributed chapters, the book's extensive coverage includes: Preparation of Elemental Fluorine Synthesis Methods for Exotic Inorganic Fluorides with Varied Applications Introduction of Fluorine into Compounds via Electrophilic and Nucleophilic Reactions Direct Fluorination of Organic Compounds with Elemental Fluorine Efficient Preparations of Bioorganic Fluorine Compounds Asymmetric Fluorocyclization Reactions Preparations of Rare Earth Fluorosulfides and Oxyfluorosulfides The book offers methods and results that can be reproduced by students involved in advanced studies, as well as practicing chemists, pharmaceutical scientists, biologists, and environmental researchers. The only chemical resource of its kind, Efficient Preparations of Fluorine Compoundsfrom its first experiment to its lastis a unique window into the centuries old science of fluorine and the limitless universe of fluorine-based compounds.

Inhalt
Foreword xi Preface xiii Contributors xv 1 Preparation of Elemental Fluorine 1
Karl O. Christe 2 Preparation of Highly Active Cesium Fluoride 7
Konrad Seppelt 3 Preparation of Highly Active Silver Fluoride 9
Konrad Seppelt 4 A Room-Temperature Non-Irradiative Synthesis of XeF2 11
Ulf Breddemann, John R. DeBackere, and Gary J. Schrobilgen 5 Efficient Perfluorination of K2B12H12 in Neutral Acetonitrile 16
Dmitry V. Peryshkov, Eric V. Bukovsky, and Steven H. Strauss 6 Efficient Preparation of the Highly Soluble ortho- and para-C60(CF2C6F5)2 Derivatives 19
Igor V. Kuvychko, Bryon W. Larson, Steven H. Strauss, and Olga V. Boltalina 7 Synthesis of Cs[1-H-CB11F11] 22
Michal Vala¡sek, Filip embera, Michael J. Hughes, Ivan Stibor, Zbyn¡ek Janou¡sek, and Josef Michl 8 Synthesis of Zero-Valent Trifluoromethyl Chalcogenato Derivatives, [NMe4]ECF3 (E = S, Se, Te), and Related Compounds 26
Wieland Tyrra and Silke Kremer 9 Synthesis Methods for Exotic Inorganic Fluorides with Varied Applications 35
Dayal T. Meshri, N. C. Mathur, and Ritesh R. Jain 10 Tris(pentafluorophenyl)borane, B(C6F5)3, a Powerful, Well-Soluble, Nonoxidizing Lewis Acid and the Weakly Coordinating Tetrakis(pentafluorophenyl)borate Anion, [B(C6F5)4] 60
Hermann-Josef Frohn 11 Pentafluorophenyldifluoroborane, C6F5BF2, and Pentafluorophenyltrifluorosilane, C6F5SiF3, Versatile Reagents for Fluorine/Pentafluorophenyl Substitution Reactions in Strongly Oxidizing Hypervalent Nonmetal Fluorides 65
Hermann-Josef Frohn 12 Iodine(III and V) Fluorides: Interesting Fluorinating Agents 72
Hermann-Josef Frohn 13 Tetramethylammonium Fluoride, [N(CH3)4]F, a Widely Applicable Reagent to Introduce Fluoride Ions and a Suitable Nucleophile to Initiate the Transfer of Perfluoroorganyl Groups to Electrophiles 76
Hermann-Josef Frohn 14 Preparation of Transition Metal Sulfide Fluorides 79
Michael Gerken 15 Transition Metal Carbonyl Sulfur Dioxide and Thiazylfluoride Complexes: Reactions at the Metal Center and at the Ligand 82
Rudiger Mews 16 Cesium, Mercury, and Silver Salts with Sulfur-Nitrogen-Fluorine Anions: Useful Transfer Reagents for NSF Building Blocks 88
Rudiger Mews 17 Laboratory-Scale Synthesis of Gold Trifluoride and Uranium Hexafluoride 94
Thomas M. Klapotke 18 Preparation of Transition Metal Fluorides using ClF3 100
Ralf Haiges 19 Preparation of Fluorine-Containing Molecular Halides and Heteropolar Salts with Elements of Group 15 and Niobium and Tantalum Halides 108
Lothar Kolditz

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