Organic Synthesis Using Samarium Diiodide

A concise practical approach to the chemistry of the versatile lanthanide reagent samarium diiodide, containing illustrative practical procedures and literature references.

Autorentext
David J Procter is Professor of Organic Chemistry at the University of Manchester, UK and has over 10 years experience as an independent academic. He is the principal author of over 40 publications and conference proceedings on the use of samarium diiodide (and other lanthanide reagents) in organic synthesis since 1999 and one of his review papers has been cited over 100 times. He has also given 56 invited UK lectures and 20 invited international lectures on the chemistry of samarium diiodide. Robert A Flowers, II is Chair and Professor of Chemistry at Lehigh University, Bethlehem, PA, USA and has 15 years experience as an independent faculty member. He is the principal author of more than 40 publications and conference proceedings on the chemistry of samarium diiodide and other lanthanide-based reagents since 1997. He has given over 40 invited US and international lectures on the mechanisms of samarium diiodide and in 2008 he was awarded the Danser Distinguished Professor of Chemistry. Troels Skrydstrup is Professor of Organic Chemistry at the University of Aarhus, Denmark and has 13 years experience as an independent academic. He is the principal author of more than 40 publications on the use of samarium diiodide (and other transition metal based single electron reagents) in organic synthesis since 1994. He has given over 50 invited lectures at various institutions and international meetings on the chemistry of samarium diiodide.

Klappentext
This book provides a concise, practical guide to the use of samarium diiodide. Although the reagent is used extensively by organic chemists there is still a widely-held view that is can be difficult to prepare and use. In addition samarium diiodide can mediate such a wide variety of reactions in organic chemistry that potential users are often overawed by the extensive primary literature. This book aims to address these misgivings and misconceptions. Rather than being a comprehensive review of the chemistry of samarium diiodide, this user-friendly book adopts an "an all you need to know" approach to the topic. It includes the best methods for preparing and handling the reagent, how solvents, co-solvents and additives alter reactivity, the basic mechanisms of reactions, common transformations using the reagent, and emerging areas in samarium diiodide chemistry. The international authors are well-known for their work with samarium diiodide and their expertise covers recent developments in new reactivity and selectivity, applications in target synthesis, co-solvent and additive effects, coordination chemistry and mechanism. The book includes the best methods for preparing and handling the reagent, how solvents, co-solvents and additives alter reactivity, the basic mechanisms of reactions, common transformations using the reagent, and emerging areas in samarium diiodide chemistry. The authors have distilled the extensive primary literature to allow the reader to quickly grasp an understanding of the reagent and its utility. The illustrative practical procedures help the reader to prepare and use the reagent in the laboratory while references from the recent literature allow readers to pursue their interest in the popular reagent.

Inhalt
Chapter 1: Introduction; Chapter 2: The reagent and the effect of additives; Chapter 3: Mechanisms of SmI2-mediated reactions - the basics; Chapter 4: Functional group transformations using SmI2; Chapter 5: Carbon-carbon bond-forming reactions using SmI2; Chapter 6: Sequential carbon-carbon bond formation using SmI2; Chapter 7: Emerging areas;

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