Name Reactions

Name Reactions

Einband:
Fester Einband
EAN:
9783540300304
Untertitel:
A Collection of Detailed Mechanisms and Synthetic Applications
Genre:
Chemie
Autor:
Jie Jack Li
Herausgeber:
Springer Berlin Heidelberg
Auflage:
3rd. expanded ed
Anzahl Seiten:
676
Erscheinungsdatum:
19.07.2006
ISBN:
3540300309

The third edition of this book on name reactions contains major improvements over the previous edition. In addition to updated references, each reaction is now supplemented with two to three representative examples in synthesis to showcase its synthetic utility. Biographical sketches for the chemists who discovered or developed those name reactions have been included. Furthemore, the subject index is significantly expanded. This book differs from others on name reactions in organic chemistry by focusing on their mechanisms. It covers over 300 classical as well as contemporary name reactions. Each reaction is delineated by its detailed step-by-step, electron-pushing mechanism, supplemented with the original and the latest references, especially review articles. Thus, it is not only an indispensable resource for senior undergraduate and graduate students for learning and exams, but also a good reference book for all chemists interested in name reactions.

Many chemists collect named and unnamed reactions and their mechanisms Will make this time-consuming effort redundant Gives the earliest and latest references to these name reactions Gives representative examples in synthesis

Klappentext
I don't have my name on anything that I don't really do. Heidi Klum Can the organic chemists associated with so-called Named Reactions make the same claim as supermodel Heidi Klum? Many scholars of chemistry do not hesi- te to point out that the names associated with name reactions are often not the actual inventors. For instance, the Arndt-Eistert reaction has nothing to do with either Arndt or Eistert, Pummerer did not discover the Pummerer rearran- ment, and even the famous Birch reduction owes its initial discovery to someone named Charles Wooster (first reported in a DuPont patent). The list goes on and on But does that mean we should ignore, boycott, or outlaw named reac- ons ? Absolutely not. The above examples are merely exceptions to the rule. In fact, the chemists associated with name reactions are typically the original dis- verers, contribute greatly to its general use, and/or are the first to popularize the transformation. Regardless of the controversial history underlying certain named reactions, it is the students of organic chemistry who benefit the most from the - taloging of reactions by name. Indeed, it is with education in mind that Dr. Jack Li has masterfully brought the chemical community the latest edition of Name Reactions. It is clear why this beautiful treatise has rapidly become a bestseller within the chemical community.

Zusammenfassung
I don't have my name on anything that I don't really do. Heidi Klum Can the organic chemists associated with so-called Named Reactions make the same claim as supermodel Heidi Klum? Many scholars of chemistry do not hesi- te to point out that the names associated with name reactions are often not the actual inventors. For instance, the Arndt-Eistert reaction has nothing to do with either Arndt or Eistert, Pummerer did not discover the Pummerer rearran- ment, and even the famous Birch reduction owes its initial discovery to someone named Charles Wooster (first reported in a DuPont patent). The list goes on and on But does that mean we should ignore, boycott, or outlaw named reac- ons? Absolutely not. The above examples are merely exceptions to the rule. In fact, the chemists associated with name reactions are typically the original dis- verers, contribute greatly to its general use, and/or are the first to popularize the transformation. Regardless of the controversial history underlying certain named reactions, it is the students of organic chemistry who benefit the most from the - taloging of reactions by name. Indeed, it is with education in mind that Dr. Jack Li has masterfully brought the chemical community the latest edition of Name Reactions. It is clear why this beautiful treatise has rapidly become a bestseller within the chemical community.

Inhalt
Alder ene reaction.- Aldol condensation.- Algar-Flynn-Oyamada Reaction.- Allan-Robinson reaction.- Appel reaction.- Arndt-Eistert homologation.- Baeyer-Villiger oxidation.- Baker-Venkataraman rearrangement.- Bamberger rearrangement.- Bamford-Stevens reaction.- Barbier coupling reaction.- Bargellini reaction.- Bartoli indole synthesis.- Barton radical decarboxylation.- Barton-McCombie deoxygenation.- Barton nitrite photolysis.- Barton-Zard reaction.- Batcho-Leimgruber indole synthesis.- Baylis-Hillman reaction.- Beckmann rearrangement.- Beirut reaction.- Benzilic acid rearrangement.- Benzoin condensation.- Bergman cyclization.- Biginelli pyrimidone synthesis.- Birch reduction.- Bischler-Möhlau indole synthesis.- Bischler-Napieralski reaction.- Blaise reaction.- Blanc chloromethylation.- Blum aziridine synthesis.- Boekelheide reaction.- Boger pyridine synthesis.- Borch reductive amination.- Borsche-Drechsel cyclization.- Boulton-Katritzky rearrangement.- Bouveault aldehyde synthesis.- Bouveault-Blanc reduction.- Boyland-Sims oxidation.- Bradsher reaction.- Brook rearrangement.- Brown hydroboration.- Bucherer carbazole synthesis.- Bucherer reaction.- Bucherer-Bergs reaction.- Büchner-Curtius-Schlotterbeck reaction.- Büchner method of ring expansion.- Buchwald-Hartwig C-N and C-O bond formation reactions.- Burgess dehydrating reagent.- Cadiot-Chodkiewicz coupling.- Camps quinolinol synthesis.- Cannizzaro disproportionation.- Carroll rearrangement.- Castro-Stephens coupling.- Chan alkyne reduction.- Chan-Lam coupling reaction.- Chapman rearrangement.- Chichibabin pyridine synthesis.- Chugaev elimination.- Ciamician-Dennsted rearrangement.- Claisen condensation.- Claisen isoxazole synthesis.- Claisen rearrangements.- Clemmensen reduction.- Combes quinoline synthesis.-Conrad-Limpach reaction.- Cope elimination reaction.- Cope rearrangement.- Corey-Bakshi-Shibata (CBS) reduction.- Corey-Chaykovsky reaction.- Corey-Fuchs reaction.- Corey-Kim oxidation.- Corey-Nicolaou macrolactonization.- Corey-Seebach reaction.- Corey-Winter olefin synthesis.- Criegee glycol cleavage.- Criegee mechanism of ozonolysis.- Curtius rearrangement.- Dakin oxidation.- Dakin-West reaction.- Danheiser annulation.- Darzens glycidic ester condensation.- Davis chiral oxaziridine reagents.- Delépine amine synthesis.- de Mayo reaction.- Demjanov rearrangement.- Dess-Martin periodinane oxidation.- Dieckmann condensation.- Diels-Alder reaction.- Dienone-phenol rearrangement.- Di-?-methane rearrangement.- Doebner quinoline synthesis.- Dötz reaction.- Dowd-Beckwith ring expansion.- Erlenmeyer-Plöchl azlactone synthesis.- Eschenmoser-Tanabe fragmentation.- Eschweiler-Clarke reductive alkylation of amines.- Evans aldol reaction.- Favorskii rearrangement and quasi-Favorskii rearrangement.- Feist-Bénary furan synthesis.- Ferrier carbocyclization.- Ferrier glycal allylic rearrangement.- Fiesselmann thiophene synthesis.- Fischer indole synthesis.- Fischer oxazole synthesis.- Fleming-Kumada oxidation.- Friedel-Crafts reaction.- Friedländer quinoline synthesis.- Fries rearrangement.- Fukuyama amine synthesis.- Fukuyama reduction.- Gabriel synthesis.- Gabriel-Colman rearrangement.- Gassman indole synthesis.- Gattermann-Koch reaction.- Gewald aminothiophene synthesis.- Glaser coupling.- Gomberg-Bachmann reaction.- Gould-Jacobs reaction.- Grignard reaction.- Grob fragmentation.- Guareschi-Thorpe condensation.- Hajos-Wiechert reaction.- Haller-Bauer reaction.- Hantzsch dihydropyridine synthesis.- Hantzsch pyrrole synthesis.- Heck reaction.- Hegedus indole synthesis.-Hell-Volhard-Zelinsky reaction.- Henry nitroaldol reaction.- Hinsberg synthesis of thiophene derivatives.- Hiyama cross-coupling reaction.- Hofmann rearrangement.- Hofmann-Löffler-Freytag reaction.- Horner-Wadsworth-Emmons reaction.- Houben-Hoesch reaction.- Hunsdiecker-Borodin reaction.- Hurd-Mori 1,2,3-thiadiazole synthesis.- Jacobsen-Katsuki epoxidation.- J…


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