Practical Heterocyclic Chemistry

Practical Heterocyclic Chemistry focuses on experiments, methodologies, processes, reactions, and transformations involved in practical heterocyclic chemistry.
The manuscript first offers information on five-membered systems containing one heteroatom and benzoderivatives of five-membered systems containing one heteroatom, including 2,5 - dimethylpyrrole, 2,5 - dimethylthiophen, carbazole, indigotin, and 2-phenylindole. The text then elaborates on five-membered systems containing more than one heteroatom and benzoderivatives of five-membered systems containing more than one heteroatom, as well as benzimidazole, benzotriazole, and 2,4,5 - triphenyloxazole.
The publication ponders on six-membered systems containing one heteroatom and benzoderivatives of six-membered systems containing one heteroatom. Discussions focus on 4-nitropyridine N-oxide, 6-chloroquinoline, 2-methyl-4-quinolone, and xanthone.
The manuscript is highly recommended for chemists and readers interested in practical heterocyclic chemistry.

Inhalt
Contents

Introduction


Preface


Chapter l: Five-Membered Systems Containing One Heteroatom


2,4-Diethoxycarbonyl-3,5-dimethylpyrrole


2,5-Dimethylpyrrole


4,5 -Diphenyl-2-Methylfuran-3 -Carboxylic Acid


2,5-Dimethylthiophen


Chapter 2: Benzoderivatives of Five-Membered Systems Containing One Heteroatom


Carbazole


1,2,3,4-Tetrahydrocarbazole


2,3-Dioxoindoline (Isatin)


Indigotin (Indigo)


2-Phenylindole


2-Benzoylbenzofuran (2-Benzoylcoumarone)


5-Hydroxycyclo-Octano[b]coumaran


2 -Methylcoumaran


5-Chloro-3-Methylbenzo [b] thiophen


Chapter 3: Five-Membered Systems Containing More Than One Heteroatom


2,4-Dioxoimidazolidine (Hydantoin)


4,5-Diphenylimidazole (4,5-diphenylglyoxaline)


2-Methyl-Imidazoline


3,5-Dimethylpyrazole


3-Methyl-1-phenyl-5-pyrazolone


l,3,5-Triphenyl-pyrazoline


3,5-Dimethylisoxazole


3 -Phenyl-5-isoxazolone


4-Benzylidene-2-phenyl-5-oxazolone


Cyclohexanespiro-2'-(l',3'-oxazolidine)


2-Methyl-oxazoline


2,4,5-Triphenyloxazole


p-Chlorophenylsydnone


3,4-Dimethyl-l,2,5-oxadiazole (3,4-dimethylfurazan)


2,5-Diphenyl-l,3,4-oxadiazole


2,4-Dimethylthiazole


2-Methyl-thiazoline


Chapter 4: Benzoderivatives of Five-membered Systems Containing More Than One Heteroatom


Benzimidazole


1,2-Dihydro-2-oxobenzimidazole (benzimidazolone)


6-Nitroindazole


l-Aminobenzotriazole


Benzotriazole


l-(p-Nitrophenyl)-4,5,6,7-tetrahydrobenzotriazole


3-Methyl-5-nitrobenzisoxazole


3 -Phenylbenzo-2,1 -isoxazole (3-phenylanthranil)


2-Methylbenzoxazole


2-Methyl-6-nitrobenzoxazole


Benzo-2,1,3-oxadiazole 1-oxide (benzofuroxan)


5(6)-Chlorobenzo-2,1,3 -oxadiazole 1-oxide [5(6)-chlorobenzofuroxan]


2-Phenylbenzo-1,3-diaza-2-borole


2-Phenylbenzo-l,3-diaza-2-phosphole 2-oxide


2-Phenylbenzo-l,3-oxaza-2-borole


2-Phenylbenzothiazole


Benzo-2,1,3 -thiadiazole


Chapter 5: Six-membered Systems Containing One Heteroatom


3-Chloro-2,6-dimethylpyridine


3,5-Diethoxycarbonyl-2,6-dimethyl-4-(m-nitrophenyl)pyridine


4-Nitropyridine N-oxide


3-Cyano-4,6-dimethyl-2-pyridone: Method 1


3-Cyano-4,6-dimethyl-2-pyridone: Method 2


3,5-Diacetyl-l,4-dihydro-2,4,6-trimethylpyridine


4-Pyridone-2,6-dicarboxylic acid (chelidamic acid)


3-Acetyl-3,4-dihydro-6-methyl-4-oxo-a-pyrone (dehydroacetic acid)


2,6-Dimethyl-y-pyrone


6-Isobutenyl-4-methyl-a-pyrone


Chapter 6: Benzoderivatives of Six-membered Systems Containing One Heteroatom


3 -Methyl-1-phenylisoquinoline


6-Chloroquinoline


4-Methyl-2-phenylquinoline


2,4,6-Trimethylquinoline


2-Methyl-4-quinolone


4-Methyl-2-quinolone


4-Phenyl-2-quinolone


9-Acridone


Phenanthridine


6-Phenanthridone


Chromone-2-carboxylic Acid


2-Methyl-5,6,7,8-tetrahydrochromone


7-Hydroxy-4-methylcoumarin (4-methylumbelliferone)


Benzo [f]chroman-4-one


Benzo [f]chromone


Xanthone


Chapter 7: Six-membered Systems Containing More Than One Heteroatom


4-Cyano-2,3-dihydro-5,6-diphenyl-3-oxopyridazine


2,4-Dioxo-6-methyl-l,2,3,4-tetrahydropyrimidine (6 -methyluracil)


Hexahydro-2,4,6-trioxopyrimidine (barbituric acid)


2,5 -Dioxopiperazine


Pyrazine-2,3-dicarboxylic acid


Hexahydro-1,3,5-tri-p-tolyl-s-triazine


Chapter 8: Benzoderivatives of Six-membered Systems Containing More Than One Heteroatom


4-Cinnolone


Quinazoline


3 - Amino-3,4-dihydro-2-methyl-4-oxoquinazoline


3,4-Dihydro-1-hydroxy-4-oxophthalazine


3,4-Dihydro-1 -methyl-4-oxophthalazine


Dibenzo [a,c]phenazine


3,4-Dihydro-4-oxo-l ,2,3-benzotriazine: Method 1


3,4-Dihydro-4-oxo-1,2,3 -benzotriazine: Method 2


2-Ethy1-4-0X0-3,1 -benzoxazine


2,3 -Dihydro-3-oxo-1,4-benzoxazine (benzo-3-morpholone): Method 1


2,3 -Dihydro-3-oxo-1,4-benzoxazine (benzo-3-morpholone): Method 2


2,4-Dinitrophenoxazine


Phenothiazine


2-Oxo-l,4-benzodioxan


Phenoxathiin


Chapter 9: Miscellaneous Systems


Cyclohexa-2,5-diene-4-one-spiro-2'-oxetano[3',4']cyclo-octane


4,6-Dinitrobenzimidazo [1,2-a]pyridine


2-Phenylimidazo[l,2-a]pyridine


2,3,4,5-Tetrahydropyrido[l,2-a]-benzimidazole


l,4-Dihydro-endo-l,4-oxanaphthalene


Bibliography


Subject Index

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