Erscheinungsdatum:
30.05.2013
Radicals and radical ions are important intermediates with wide use in organic synthesis. The first book to concentrate on reagents for the creation and use of radicals and radical ions, this new volume in the Handbooks of Reagents for Organic Synthesis series compiles articles taken from the e-eros database, on reagents for use in radical and radical chemistry, to help the chemist in the lab choose the right reagents. Reflecting the enormous growth of radical chemistry over the past ten years, this is an essential guide for all synthetic chemists.
Autorentext
David Crich, BSc, Surrey University, 1981; DEsSc, University of Paris, 1984; Postdoctoral Fellow, Institut de Chimie des Substances Naturelles, 1984-1985; Lecturer, University College, London, 1985-1990; Laureat of the Academy of Sciences (France) 1989; Corday Morgan Medal (Royal Society of Chemistry), 1990; University of Illinois Scholar, 1992; Visiting Professor, University of Aix-Marseille, 1992: Fellow of the A. P. Sloan Foundation, 1994-1996; Tate and Lyle Carbohydrate Chemistry Medal (Royal Society of Chemistry), 1995. Since1997 Distinguished Professor of Organic Chemistry at the University of Illinois at Chicago. Since 2001 on the Editorial Board of e-EROS.
Klappentext
Radicals and radical ions have long surpassed their image as highly reactive, uncontrollable intermediates unsuitable for application in fine chemical synthesis. Nowhere is this more apparent than in the area of stereoselective radical reactions which, as recently as the 1980s, were considered unlikely, but which, with improved methods for radical generation, now compete on an equal footing with their more familiar two electron counterparts. Unfortunately, most undergraduate organic chemistry textbooks still introduce budding chemists to radical reactions through the chlorination of methane, and so convey the erroneous general impression of complex and unselective chemistry. The goal of this Handbook is to illuminate the broad selection of reagents available for open shell reactions, and to illustrate the wide variety of highly selective transformations that may be highly selective transformations that may be readily achieved with high degrees of functional group compatibility through their use. Accordingly, it is hoped that the Handbook will stimulate the ever wider use of radical and radical ion-based transformations in synthetic organic chemistry. All the information compiled in this volume, along with many more reagents of other types and uses, is also available in electronic format on Wiley Interscience in the electronic Encyclopedia of Reagents for Organic Synthesis (e-EROS). e-EROS offers text and structure searching and is supplemented twice a year with the addition of many new and updated entries. To see the complete collection of organic reagents online visit: http://www/mrw.interscience.wiley.com/eros/
Inhalt
Preface. Introduction. Selected Monographs and Reviews. Acrylonitrile. Allyl Ethylsulfone. Allyltributylstannane. Allyltriphenylstannane. 4,4' -Azobis(4-cyanopentanoic acid). 1,1' -Azobis-1-cyclohexanenitrile. 2,2'-Azobis(2,4-dimethyl-4-methoxyvaleronitrile). 2,2'-Azobis[2-(imidazolin-2-yl)-propane] Dihydrochloride. Azobisisobutyronitrile. 2,2'-Azobis(2-methylpropanimidamide) Dihydrochloride. Benzeneselenol. Benzenesulfonyl Azide. 1,2-Benziodoxol-3(1H)-one Derivatives. 4,5-Bis (1,1-dimethylethyl)-6-ethoxy-2,2-dimethyl-3,7-dioxa-4-aza-6-phosphanonanoic Acid 6-oxide. Bis(dimethylglyoximato)(methyl)(pyridine)cobalt (III). Bis(ethoxythiocarbonyl)sulfide. Bis[(1R,2S,5R)-menthyl](phenyl)tin Hydride. Bis[4-(tridecafluorohexyl)phenyl]Diselenide. Bis(trimethylstannyl) Benzopinacolate. Bromine Azide. Bromine Trifluoride. (1-Bromoethenyl)chlorodimethylsilane. (Bromomethyl)chlorodimethylsilane. N-Bromosuccinimide. Bromotrichloromethane. t-Butyl Hydroperoxide. t-Butyl Hypochlorite. t-Butyl Hypoiodite. t-Butyl Isocyanide. N-t-Butyl- 1 -diethylphosphono-2,2-dimethylpropyl Nitroxide. Carbon Monoxide. Carbon Tetrabromide. Carbon Tetraiodide. Catecholborane. Ceriuim (IV) Ammonium Nitrate. Chlorobis(dimethylglyoximato) (pyridine)cobalt (III). N-Chloro-N-cyclohexylbenzenesulfonamide. 4-(4-Chlorophenyl)-3-hydroxy-2(3H)thiazolethione. Chromium(II) Acetate. Chromium (II) Chloride. Cobalt Salen Complexes. Cobalt Salophen Complexes. Copper(II) Acetate. 1,4-Cyclohexadiene. Decacarbonyldimanganese. (Diacetoxyiodo)benzene. Dibenzoyl Peroxide. Di-t-butyl Hyponitrite. 1,1-Di-t-butyl Peroxide. 2,2-Di(t-butylperoxy)butane. Di-t-butyl Peroxyoxalate. N,N-Dichlorobenzenesulfonamide. 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone. Dilauroyl Peroxide. 1,4:5,8-Dimethano-1,2,3,4,5,6,7,8-octahydro-9,10-dimethoxyanthracenium Hexachloroantimonate. (2,6-Dimethoxy-1-methyl-2,5-cyclohexadien-1-yl) (1,1-dimethylethyl)dimethylsilane. [2-(Dimethylamino)methyl]phenyl Dimethyltin Hydride. 2,2-Dimethyl-5-[3-(diphenylstannyl)propyl]-1,3-dioxolan-4-one. Dimethyl Disulfide. 5,5-Dimethyl- 1-(phenylmethyl)-3-pyrazolidinone. Dimethyl[3-(1-pyrenyl)propyl]stannane. Diphenyl Diselenide. Diphenyl Disulfide. Diphenyl Disulfone. Diphenyl Ditelluride. Diphenyl[2-(4-pyridyl)ethyl]tin hydride. 2,2'-Dipyridyl Disulfide N,N'-Dioxide. t-Dodecanethiol. Ethanesulfonyl Azide. Ethyl Difluoroiodoacetate. Galvinoxyl. Hexabutyldistannane. Hexamethyldistannane. Hydrogen Bromide. Hydrogen Selenide. N-Hydroxyphthalimide. N-Hydroxypyridine-2-thione. Hypophosphorous Acid. Indium. Iodine Azide. Iodine-Nitrogen Tetroxide. 2'-Iodobiphenyl-2-thiol Dimethylaluminum Complex. Iodoform. Iodosylbenzene. 1-Iodo-2-(2,2,2,-triethoxyethyl)benzene. Iron, Bis(pyridine)bis(2-pyridinecarboxylato-N1,02). Iron(III) Chloride. Lead(IV) Acetate. Lead(IV) Acetate-Copper(II) Acetate. Lead(IV) Acetate-Iodine. Lithium 4,4'-Di-t-butylbiphenylide. Lithium 1-(Dimethylamino)naphthalenide. Lithium Naphthalenide. Manganese(III) Acetate. Manganese(III) Acetate-Copper(II) Acetate. Manganese(III) Acetylacetonate. Mercury(II) Oxi...
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